Using a mixture of gold, copper and platinum nanoparticles, researchers have developed a more powerful and longer lasting fuel cell material. Fuel cells are a promising technology for use as a source of electricity to power electronic devices, vehicles, military aircraft and equipment.
A fuel cell converts the chemical energy from hydrogen into electricity through a chemical reaction with oxygen. Current commercially available fuel cells use platinum nanoparticles as the catalyst to speed up the chemical reaction because platinum is the only metal that can resist the highly acidic conditions inside such a cell. However, the widespread use of fuel cells has been impeded by the high cost of platinum and its low stability.
ü To overcome this limitation, a team of researchers, have discovered that by replacing the central part of the catalyst with gold and copper alloy and leaving just the outer layer in platinum, the new hybrid material can provide five times higher activity and much greater stability than the commercial platinum catalyst. With further optimization, it would be possible to further increase the material's catalytic properties.
ü To make this catalyst more active than the commercial platinum catalyst, the researchers have designed the core of the nanocrsytalline material to be a gold-copper alloy, which has slightly smaller lattice spacing than the platinum coating on the nanocrystal's surface. This creates a compressive strain on the surface platinum atoms, making the platinum more active in the rate-limiting step of oxygen reduction reaction for the fuel cell. Replacing the core of the nanoparticle with the less expensive gold-copper alloy cuts down the usage of platinum, a highly expensive noble metal.
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